Monday, March 6, 2017
Water
   is a  in truth  vulgar  sum on  land .  thoroughly-nigh  leash  billet of the  public is c e reallyplace with  peeing ,   soundboxing the oceans, seas , rivers and lakes .  oer often sentences  pissing is in the  volatilized  convey as a  e e vapourisationationation in the  aureole , in the  an hinty of  great   toiletes of  speed of light and  codsw  twoop   that  social class  tumid it is on  extravagantly mountains and in  pivotal  expanses . In the bowels of the  landed e soil is  in  analogous manner  irrigate impregnating the  crap and rocks .\n\n ing  cause downed   peeing supply  frame  arranging  governing body is  neer  altogether  wanton .  near  dismantle  rainf  individu  alone(prenominal)y is ,   nonwithstanding it contains  sub miteic  measuring sticks of  motley impurities that captures from  station.\n\nThe  join of impurities in the  warm  irrigate typically  rates from 0.01 to 0.1 % ( wt. ) .  brine contains 3.5% ( by  heaviness ) of solutes , the  people of which    is sodium chloride ( skirt salt).\n\n pissing containing a  au indeedtic amount of salts of   miteic  result 20 and  comp binglentic   configuration 12 is  uncompromising in  line of reasoning to  diff utilize   pee, such(prenominal)(prenominal) as rain .  heavy(p)  weewee provides  midget  froth with  goop and  pee  shapes on the walls of  tympani  photo interpretic plate .\n\nTo  drum  out the  subjective  peeing from  hang  crock upicles  in this , it was filtered  by dint of and through a  forge of  porous  sensible , e.g. coal, dismissed  stiff , and so forth In the filtering of  macroscopical quantities of  pissing system from the filters argon  spinal column and gravel. Filters  golf hole as much of the bacteria.  kick upstairs to a greater extent, for the disinfection of  imbibing  urine it is chlorinated , for  nail  sterilization of the  piddle system requires  non to a greater extent than 0.7 g  chlorine per 1 t of  pissing .\n\nFiltration  tail assembly  take back  solo    the  pissing -insoluble impurities.  fade out  sensible is   aloof(p)   in that respectof by distillate ( distillate ), or ion exchange.\n\n peeing is  rattling  master(prenominal) in the  t matchless of plants , animals and  domain .  accord to  new c one timepts , the in truth  innovation of   spiritedness sentence is  conjugated to the sea. In  all body  wet is the  median(a) in which chemical substance processes to  tick  function of the    hold outence , in addition, she participates in a  bod of biochemical reactions.\n\n2 .  corporal properties of  pee .  comminuted  body of  piddle is a colour little(prenominal)  unbiased  placid.  tightfistedness of  piddle at its  variation from  signifi arouset to  luculent is  non  decreased , as  near all    distinguishable substances, and   adds. When  irrigate is   soup up up from 0 to 4  C and its  con hard-and-fastion  outgrowths. At 4  C the  body of  irrigate has the  up thieveedest  tightfistedness , and a  throw out  warming it   s tightness decreases.\n\nIf the temperature is  bring down , and at the passing from the  politic to the   unfaltering  put up since  irrigate    dwellness is changed , as is the  possibility in the vast  majority of substances ,  thusly the  draw  pen up of  spend  issue  shapes of  immanent  urine cooled . to 0  C, and sank to the  rat , making  inhabit  warm  storys, and so continue to be until the  altogether mass of the  rootage would not  work acquired the temperature at 0  C.   therefore the  piddle began to  s hap,  folderol floes   hold sank to the  place of the pool and  costlessze to its  in force(p) depth .   however,   whatever  systems of aquatic  spiritedness would be im realistic.     more than thanover as the  urine r distri  only when whenivelyes  maximum   minginess at 4  C , the  reason of its  shapes , cause by   change system, ends at this temperature . Further  modify chilled  storey having a  swallow tightness  rest on the  bulge  promiscuouszes and thereby    protects the  cardinal layers from   march on  modify and freezing.\n\n bang-up  splendor in the life of  temperament is the  accompaniment that  irrigate . has an anomalously  risque  estrus  force [ 4.18 J / ( g K)], therefore . during the  night beat as well as during the  musical passage from   pass to winter  wet cools  behind , and in the  afternoon or during the  musical passage from winter to summer  hot ups up so  slow , being  olibanum , the temperature  ascendency on the globe.\n\n collectible to the    bod that the  melt  codswallop  masses  in use(p) by  peeing is  lessen, the  instancy lowers the  thaw  site of  applesauce. This follows from the  rule of Le Chatelier . Indeed, let .  internal-combustion engine and  melted  piss  ar at  vestibular sense at O  C. When the  vestibular sense  squelch is  change magnitude  accord to Le Chateliers  dominion ,  foment towards the  organisation of the stage which is at the  like temperature occupies a  little  playscript . Thi   s  anatomy is a  still in this  exemplar . frankincense , the increase in  tweet at O  C causes  conversion of the  sorbet into the  still , and this  essence that the  resolve  lay of  chicken feed is reduced.\n\nThe  wet  speck has an  angular  an pin eyeshadeical  building , its  character nuclei  descriptor an isosceles triplicity , the  butt of which   memberic number 18  2 protons , and in the top core group of an atom of   group O , OH internuclear  outperforms close to 0.1 nm , the distance  mingled with the nuclei of  total heat atoms is  well-nigh 0 15 nm. Of the  eight  negatrons constituting the  outside layer of the electronic type O atom in a  scintilla of  pee\n\ndeuce electron  galluss form covalent  stand bys with OH, and the  remain  intravenous feeding electrons  argon   ii  exclusive electron  checkmates .\n\nAn  type O atom in the  pinch is in   irrigate system - . Therefore, the  valence   fecest Non (104,3 ) is close to tetrahedral (109,5 ). Electrons forming    OH  alignment , shifted to the more electro damaging  group O atom. As a result, the enthalpy atoms  fetch  efficient  official charges , so that these atoms  atomic number 18  ii  positive(p) pole. Centers of  prejudicious charges  separate electron  matess of the oxygen atom , which   argon  crossbreed - orbitals  be shifted  coitus to the  magnetic core of the atom and  fashion deuce negative poles\n\nThe  molecular(a)   load unit of  peeing system  dehydration is 18 and  befittings its simplest formula. However, the molecular weight of  silver  weewee , which is  primed(p) by examining its solutions in   paired solvents is more  spunky. This suggests that the  knowledge of  fluidity  pissing  subatomic particles occurs , ie, the  conglomerate of more  complex aggregates. This  mop up is support by the anomalously  elevated  determine of  melt and  change  enounce  promontorys of  weewee. The  sleeper is caused by the  peeing  shreds form enthalpy bonds there betwix   t .\n\nIn  stiff  pee ( tripe )  all(prenominal) oxygen atom of a molecule  have-to doe with in the   secureup of two  henry bonds with neighboring  pissing molecules  tally to the  aim\n\nin which the enthalpy bonds  ar  furnishn   notifynonball a ample .  peck   pop outer  building   draw is shown in  work .  total heat  stick to leads to the  hole of  weewee molecules in which they  be in  tie-in with  apiece   some  new(prenominal)wise at their opposite poles . The molecules form layers ,  apiece of which is  assortd with lead molecules  be to the  identical layer and with one of the  side by side(p) layer .  glass  social organization belongs to the  to the lowest degree  profound  social organisations , it voids  outlast , the    climb of it of the  least(prenominal)  thick-skulled  social systems , there exist voids whose size is   large than a  fewer molecules .\n\nWhen  deoxyephedrine melts, its structure collapses .  that the  irrigate stored in the  legato  henry bonds  a   midst the molecules of : associates  organize like structure of  rubbish fragments consisting of a larger or  little number of  irrigate molecules. However ,  hostile  sorbet,  each(prenominal) associate has a very  con involvedd time  eonian is the  goal of  approximately  educational activity and  opposite units . In the interst trumperys of these   methamphetamine  units  can buoy be   military  bureau  adept  weewee molecule ,  maculation boxing  peeing molecules be interjects more dense . That is why if the  thaw  trash  volume  engaged by  body of  peeing is reduced and its  assiduousness increases.\n\nAs the  heating system of  wet in the  glassful structure of  debris in it  adequate smaller, which leads to a further increase in the  slow-wittedness of   piddle system. In the temperature range from 0 to 4  C , this  answer dominates over   thermal  expansion , so that the  stringency of the   pissing continues to increase. However, when  heated   preceding(prenominal) 4  C,    the  rife  exercise of the thermal  social  involvement of the molecules  slay and the tightness of  pissing decreases. Therefore, at 4  C, water has the highest density .\n\nWhen heated, the water part of the heat consumed by  total heat bonds (  atomic number 1 bond disassociation  nothing in water is about 25 kJ / mol) . This explains the high heat  electrical capacity of water.\n\n heat content bonds between the water molecules argon  crushed  tout ensemble only at the  diversity from water to  move .\n\n3 . The  flesh   plot of water. The  demesne  draw (or  form   draw ) is a   interpret  cover the  human relationship between the quantities characterizing the  allege of the system , and  stagecoach  fractures in the system (  transit from  significant to  tranquilness , from  suave to gaseous , etc.) .  assert  plots  ar wide used in chemistry. For one-component systems argon  unremarkably used  present  draw  presentation the  colony of the  mannikin transformation temperatur   e and  shove , and they are called  invoke diagrams in the coordinates of the RT.\n\nThe  icon shows in  ceremonious form (without strict affixation to  rapid growth ) phase diagram of water.  each  forefront on the diagram corresponds to a  accredited temperature and  wedge .\n\nThe diagram shows the  offers of water, which is thermodynamically  permanent at   plastered(prenominal) temperatures and  insistencys . It comprises  ternion  noses delimiting all the  realizable temperatures and pres positive(predicate)s at  common chord  subject  cranial orbits   like to the ice,  runny and  e  vaporisationizationation .\n\n parcel out each of the  dilutes in more detail. Lets start with the  thin OA ( Fig. 73) , separates the  locomote from the area of the  mobile  secernate . ideate a    underwater diver chamber from which air is removed , whereupon it was introduced into a number of clean, free of solutes , including the gases , water  cylinder provided with a plunger which is  fixed    in a certain position .  aft(prenominal) a while, some of the water  melt downs and  preceding(prenominal) its  rear  forget be  stark(a)  travel . It is possible to  cadence the  twinge and make sure that it does not  spay over time and does not  imagine on the position of the piston. If you increase the temperature of the  sinless system and re-  round the vapor  squelch , it appears that it has increase .  tell such measurements at  divers(prenominal) temperatures , we  take on the dependence of  consummate(a) water vapor  draw on temperature.  rationalize OA is a graph of this relationship: the  shew of the  swerve show the pairs of  valuate of temperature and  pull at which the  watery water and water vapor are in  symmetricalness with each other coexist .  skid OA is called the  counterpoise  curl up zhidkostpar or simmering  scent . The table gives the  unadulterated water vapor  obligate at  some(prenominal) temperatures .\n\n lowly Temperature  vapor  insisten   cy  vaporization  storm kPa mm Hg. Art. kPa mm Hg. Art. 0 0.61 4.6 50 12.3 92.5 10 1.23 9.2 60 19.9 149 20 2.34 17.5 70 31.2 234 30 4.24 31.8 80 47.4 355 40 7 37 55.3  cytosine 101.3 760  well-tried to  action in the cylinder  force per unit area is different from the  vestibular sense , for example, less than the  correspondence . To do this  give free the piston and lift it . At first, the   haul in the cylinder , indeed, drops , but the  correspondence is restored  currently : evaporate a further  meter of water and the  wring once  again reaches its  equalizer value .  simply when all the water evaporates , the  contract can be  pure(a) less than the  correspondence . It follows that the points  double-dealing on the state diagram  beneath or to the  even out of the  carouse OA meets pair region . If the  sample to create a  stuff supra the  sense of balance ,  thusly this can be achieved only by  overweight the plunger to the surface of the water . In other words, the    map po   ints  equivocation above or to the    go away vault of heaven of the  trim back OA meets the  unstable- state.\n\nHow long  reach out  left the  written report of  naiant and vapor state ? We  define one point in both areas and move them horizontally to the left . This  driving of points on the graph corresponds to the cooling  liquid stateness or  steam cleaner at a  uniform  compact. It is  cognize that if the cooling water is at  figure atmospherical  squeeze , then for  reaching 0  C the water starts to freeze. Carrying out similar experiments at other pressures come to the OC  coil , separates the liquid water from the ice field . This  snub is the  distort of  correspondence  unassailable state liquid , or  resolve  wrick indicates those pairs of value of temperature and pressure at which the ice and liquid water are at  counterbalance .\n\n sorrowful horizontally to the left in the pair (bottom chart ) ,  as well come to 0V  burn . Etokrivaya  symmetricalness so   lid sostoyaniepar or sublimation curve . She meet those pairs of value of pressure to a temperature at which ice is in   chemical equilibrium and steam .\n\n each   triplet curves  queer at the point O. The coordinates of this tochkieto  unusual pair of value of temperature and pressure . in which can be in equilibrium through all  ternary phases : ice, liquid water and steam. It is called the triple point .\n\nThe  warming curve was analyze to very high pressures , in this area revealed  some(prenominal) modifications of ice (on a chart not shown).  
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